Hi Harry
Have used JB weld on my rat bike a Honda cb650. The Head leaks oil all over the place when the 6mm rocker enclosure bolts go loose and strip the threads also used JB weld on the join of the head and rocker enclosure good results looks ok if you are blind.
Great success Jb weld takes heat and metal expansion ok and lasts for as long as you want. Not sure about fins as there`s not a lot of meat to get going on with, may weld ok but could be fragile to a knock.
Most HT paints will be ok on a cylinder head, make sure the one you choose has the right finish flat,matt,gloss. Andy