Hi Rob,
I don't know where the BSA fans are hiding! Removing the bungs over the valves is tricky. WHatever you do, don't holt the barrel in the vice when you do it - the bore will disort if you grip it by the bottom flange. Is the motor still in the bike? If so, do it there. You need a very close-fitting ring spanner or socket (hexagon preferred), and perhaps a bit of filing to get the hexagons on the caps back into shape. If possible put some gentle heat into the barrel (soft flame like gas, not oxy, spread gently and evenly over the whole top of the cylinder - if you can's be gently and even, don't use heat). If the spanner/socket fits well, either give it a good yank (with appropriate extension) or a "gentle" whack with a mallet/copper hammer. They might come undone. If not, I recommend drilling or machining them out. A neat line of overlapping holes from close to the thread on one side to close the thread on the other will allow some collapse of the cap, and you should be able to unscrew it easily.
Of course this doesn't help if you're not going to re-use the barrel. Perhaps if you let us know your location, someone might be able to suggest a source.
Leon